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  • Organic Chemistry  (11)
  • Dyes, fluorescent  (3)
  • Cyclophanes  (1)
  • 1
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1998 (1998), S. 1915-1917 
    ISSN: 1434-193X
    Schlagwort(e): Cyclophanes ; Fluorescent dyes ; Perylenes ; Exciton coupling ; Chemistry ; General Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Dynamic processes, a bathochromically shifted fluorescence, and strong solvent-induced chirality effects are observed for the [12,12]-perylene-bis(imide)-cyclophane 3, which forms a “fixed supramolecule”.
    Materialart: Digitale Medien
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  • 2
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1995 (1995), S. 481-486 
    ISSN: 0947-3440
    Schlagwort(e): Dyes, fluorescent ; Perylene derivatives ; Heterocyclic rings ; Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Perylene-3,4:9,10-tetracarboxylic acid 3,4-anhydride-9,10-imides are condensed with primary diamines to a number of new basic chromophores with amidine-imide structures. Lightfast dyes are obtained which exhibit a strong fluorescence in solution. The absorption and fluorescence spectra of the title compounds are bathochromically shifted compared to those of the perylene dyes.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 339 (1997), S. 597-602 
    ISSN: 0941-1216
    Schlagwort(e): Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Readily soluble, photostable and highly red fluorescent dyes (3-5) have been obtained from a condensation of perylenetetracarboxylic bisanhydride with primary aliphatic 1,3-diamines containing two geminal long-chain alkyl groups. Analogous red fluorescing dyes have been prepared by the condensation of a corresponding perylene anhydride imide.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 4
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1996 (1996), S. 1587-1591 
    ISSN: 0947-3440
    Schlagwort(e): Perylenes ; Heterocycles ; Fluorescent dyes ; Fluorescent labelling ; Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Pyrrolo- and thiophenoperylenedicarboximides 4 and 7 were prepared by reductive cyclization of 1-nitroperylenedicarboximides 3 and 5 with phosphorous acid esters and sulfur, respectively. The imides 4 and 7 are highly fluorescent and are easily monofunctionalized by nucleophilic substitution reactions which makes them useful for fluorescent labeling.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 5
    ISSN: 0947-3440
    Schlagwort(e): Fluorescent dyes ; Pigments ; Perylenes ; Carboximides ; Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Perylene-3,4-dicarboximides 2 are obtained by a decarboxylizing condensation of moderately sterically hindered primary amines with perylene-3,4,9,10-tetracarboxylic 3,4:9,10-bisanhydride (3) in the presence of water. Perylene-3,4-dicarboxylic anhydride (4) is prepared by hydrolysis of the imides with KOH in tert-butyl alcohol. The anhydride may be condensed with any primary amine to the corresponding imide. The imides are highly fluorescent and very photostable dyes.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 338 (1996), S. 654-659 
    ISSN: 0941-1216
    Schlagwort(e): Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Three perylene tetracarboxylic bisimide chromophores have been attached to a benzene ring in m-position (3). In this way steric and through-bond interactions of the chromophores are minimized and their through-space-interactions can be studied for which an unusually high bathochromic shift has been found. This indicates a destabilization. No exciton coupling has been observed in the trichromophoric dyes.
    Zusätzliches Material: 1 Ill.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1997 (1997), S. 467-468 
    ISSN: 0947-3440
    Schlagwort(e): Decarboxylation ; Carboxylic acids ; Fluorescence spectroscopy ; Perylenes ; Heterocycles ; Dyes ; Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Perylene-3,4-dicarboxylic anhydride (3) is prepared from technical grade perylene-3,4:9,10-tetracarboxylic anhydride (1) in 25% yield by a partial decarboxylation reaction using noncondensing amines. Perylene-3-carboxylic acid (4) and perylene-3,4-dicarboxylic imide (5) are prepared in the same way in yields of 24% and 76%, respectively, by a variation of the reaction conditions.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
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  • 8
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1997 (1997), S. 1151-1153 
    ISSN: 0947-3440
    Schlagwort(e): Fluorescent dyes ; Perylenes ; Heterocycles ; Photosynthesis reaction center ; CD effects ; Chemistry ; Organic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The synthesis of a bifluorophoric perylene dye (4a) is described, in which the two chromophores are linked by a chiral binaphthyl unit. A strong exciton coupling of the two chromophores, a bathochromically shifted fluorescence and strong CD effects are observed. The structure of 4 is compared to the photosynthesis reaction center.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 9
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 123 (1990), S. 1881-1884 
    ISSN: 0009-2940
    Schlagwort(e): 1,7-Diazaperylene ; Dyes, fluorescent ; Fluorescence, slid-state ; Meerwein arylation ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Synthesis of 1.7-DiazaperyleneThe hitherto unknown 1,7-Diazaperylene (2) has been prepared in a five-step synthesis from 1,5-diaminoanthraquinone (3) by a Meerwein arylation reaction. Applications as a fluorescent dye are discussed.
    Materialart: Digitale Medien
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  • 10
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 123 (1990), S. 1981-1987 
    ISSN: 0009-2940
    Schlagwort(e): Rubicene ; Hydrocarbons, polycyclic ; Dyes, fluorescent ; Singlet oxygen sensitizer ; Chemistry ; Inorganic Chemistry
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Synthesis of Highly Pure Rubicene and Rubicene DerivativesA simple one-step synthesis of highly pure rubicene (2) from fluorenone (1) and magnesium with 24% yield is described and compared with other preparation procedures. Mono- and disubstituted rubicene derivatives are prepared by electrophilic aromatic substitution.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
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