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  • 1
    ISSN: 1435-1536
    Keywords: Poly(oxetane) ; poly(3,3-dimethyloxetane) ; poly(3,3-diethyloxetane) ; crystallization behaviour ; DSC curves ; X-ray diagrams
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The influence of the crystallization temperature on the melting behaviour and crystalline structure of polyoxetane (PTO), poly(3,3-dimethyloxetane) (PDMO) and poly(3,3-diethyloxetane) (PDEO) has been studied using differential scanning calorimetry (DSC) and X-ray techniques. When PTO is crystallized by cooling from the relaxed melt state, only the orthorhombic modification is obtained. However, PDMO and PDEO can be crystallized in two different modifications depending on crystallization temperature. The effect of the substituents in the stability of main chain conformations in crystalline state is discussed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ [u.a.] : Wiley-Blackwell
    Journal of Orthopaedic Research 1 (1983), S. 431-449 
    ISSN: 0736-0266
    Keywords: Fracture healing ; Bone remodeling ; Fixation plates ; Internal fixation ; Life and Medical Sciences
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Notes: In the application of “rigid” plates for diaphyseal fractures, lack of callus healing and overprotection of the underlying bone are viewed by many investigators as undesirable consequences. Potential solutions offered to overcome these deficiencies include modification of the timing of plate removal, use of biologically degradable materials for plates so that stressshielding can be minimized, and use of less rigid plate fixation systems. This study emphasizes the selection of appropriate design criteria for less rigid plate-fixation systems. To accomplish this goal, the axial, bending, and torsional stiffness parameters are considered in place of the oversimplified terms such as “flexible plate” or “elastic fixation.” With the aid of finite element modeling and simplified bench experiments, we performed parametric studies and singled out the plate axial stiffness as the dominant factor in altering the bone stresses. As a result, we designed two experimental plates, one a thin Ti-6Al-4V (titanium with 6% aluminum and 4% vanadium) alloy plate with low stiffness in axial and bending directions, and the other a tubular stainless steel plate with low stiffness in the axial direction but moderate stiffness in bending and torsional directions. The low-stiffness Ti-6Al-4V alloy plate was first tested in a demanding bilateral canine midshalt osteotomy, and proved to be inadequate. Both experimental plates were successful in the unilateral osteotomies, with the tubular plate yielding the best results. After 6 months of plating, the bones beneath the tubular plate had superior mechanical and structural properties as compared to those of the control “rigid” stainless steel and the Ti-6Al-4V alloy plates. Application of this plate prolonged for 9 months did not cause reduction in bone properties and strength. The success of the tubular plate is due to its moderate bending and torsional stiffnesses, which provide adequate fixation to achieve callus union, while its low axial stiffness permits the underlying bone to share the physiological stresses needed for bone remodeling. These drastic changes in mechanical demands on the internal fixation plate during the early healing phase and the postunion remodeling phase are discussed.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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