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  • Energy Balance  (1)
  • bis-dienes  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Tetrahedron Letters 35 (1994), S. 73-76 
    ISSN: 0040-4039
    Keywords: Repetitive Diels-Alder reactions ; bis-dienes ; bis-dienophiles ; endo-stereoselectivity
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Space science reviews 90 (1999), S. 141-148 
    ISSN: 1572-9672
    Keywords: Comets ; Ices ; Energy Balance ; Molecular Flux
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Surface temperature and the available effective energy strongly influence the mass flux of H2O and minor volatiles from the nucleus. We perform computer simulations to model the gas flux from volatile, icy components in porous ice-dust surfaces, in order to better understand results from observations of comets. Our model assumes a porous body containing dust, one major ice component (H2O) and up to eight minor components of higher volatility (e.g. CO, CH4, CH3OH, HCN, C2H2, H2S), The body's porous structure is modeled as a bundle of tubes with a given tortuosity and an initially constant pore diameter. Heat is conducted by the matrix and carried by the vapors. The model includes radially inward and outward flowing vapor within the body, escape of outward flowing gas from the body, complete depletion of less volatile ices in outer layers, and recondensation of vapor in deeper, cooler layers. From the calculations we obtain temperature profiles and changes in relative chemical abundances, porosity and pore size distribution as a function of depth, and the gas flux into the interior and into the atmosphere for each of the volatiles at various positions of the body in its orbit. In this paper we relate the observed relative molecular abundances in the coma of Comet C/1995 O1 (Hale-Bopp) and of Comet 46P/Wirtanen to molecular fluxes at the surface calculated from our model.
    Type of Medium: Electronic Resource
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