Library

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 32 (1992), S. 343-350 
    ISSN: 1573-0867
    Keywords: Partially acidulated phosphate rocks ; extraction methods ; solubility determinations ; contaminant effects
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Methods of obtaining “reactive” phosphate rock residues from multicomponent phosphate fertilisers which contain soluble phosphorus components have been examined. Extraction using cold neutral ammonium citrate has been found to be more suitable than water, as chemical reactions appear to occur in water extraction solutions to modify the residue, and more impurity species such as calcium sulphate and iron and aluminium phosphates remain in the residues to complicate the process of obtaining reliable solubility figures. “Deactivation” of the phosphate rock residues (as measured by decreased 2% formic acid solubilities) was found to be due to reactions occurring during the maturing process, and was dependent on the phosphate rock used, with North Carolina phosphate rock-based residues significantly affected, but Arad-based residues almost unaffected. However, for neutral ammonium citrate extractions, only North Carolina-based residues produced solubility figures lower than the original phosphate rock. Some selectivity of reaction in single superphosphate-“reactive” phosphate rock mixtures was indicated which further complicated assessment of the “deactivation” effect; however such an effect appeared to be much less significant than previously suggested.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 31 (1992), S. 137-149 
    ISSN: 1573-0867
    Keywords: Extraction techniques ; partially acidulated phosphate rocks ; phosphate rock solubilities ; water solubilities ; neutral ammonium citrate solubilities ; 2% citric acid solubilities ; 2% formic acid solubilities
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Alternative extraction techniques for assessing the ‘available P’ content in multi-component fertilisers such as partially acidulated phosphate rocks have been examined. Two types of double extraction method have been investigated, one involving sequential extraction procedures, and a second examining both the initial fertiliser and its residue independently, using either water or cold neutral ammonium citrate as the first extractant, and either 2% citric or 2% formic acid as the second solvent. The latter method, which used cold neutral ammonium citrate as the initial extractant, produced the most consistent results and provided a reproducible assessment of the solubility of the phosphate rock residue; it was not obvious which second solvent was preferable. Comparisons between the original phosphate rocks and their extracted residues indicated that there were many subtle influences which affected the solubility of the phosphate rock components, but a general ‘deactivation’ of phosphate rock residues on acidulation as previously suggested was not apparent. Before any particular method can be recommended as an alternative to existing one step extraction techniques it is necessary to confirm its validity through agronomic trials.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...