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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 31 (1992), S. 111-118 
    ISSN: 1573-0867
    Keywords: Chemical analyses ; phosphate rock deactivation ; phosphate rock residue analysis ; single superphosphate—‘reactive’ phosphate rock mixtures ; partially acidulated phosphate rocks
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract The chemical analyses of different size fractions of a variety of commerical and laboratory prepared samples of partially acidulated phophate rocks and mixtures of ‘reactive’ phosphate rock and single superphosphate (called LONGLIFE in New Zealand) have been studied. Whereas only minor chemical segregation effects have been observed for partially acidulated products quite a large bias has been established for LONGLIFE materials, and more especially commercial samples, where larger proportions of phosphate rock were found in the lower size fractions. This inhomogeneity was considered to arise from poor mixing of components and subsequent inconsistent granulation; more stringent rejection criteria for undersize material would greatly assist in improving the product quality. Chemical ‘deactivation’ of the phosphate rock residue in LONGLIFE materials was also observed; this can be partially explained by a selective reaction of the ‘reactive’ phosphate rock component with acid still present at the time of mixing with the single superphosphate component.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 31 (1992), S. 137-149 
    ISSN: 1573-0867
    Keywords: Extraction techniques ; partially acidulated phosphate rocks ; phosphate rock solubilities ; water solubilities ; neutral ammonium citrate solubilities ; 2% citric acid solubilities ; 2% formic acid solubilities
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Alternative extraction techniques for assessing the ‘available P’ content in multi-component fertilisers such as partially acidulated phosphate rocks have been examined. Two types of double extraction method have been investigated, one involving sequential extraction procedures, and a second examining both the initial fertiliser and its residue independently, using either water or cold neutral ammonium citrate as the first extractant, and either 2% citric or 2% formic acid as the second solvent. The latter method, which used cold neutral ammonium citrate as the initial extractant, produced the most consistent results and provided a reproducible assessment of the solubility of the phosphate rock residue; it was not obvious which second solvent was preferable. Comparisons between the original phosphate rocks and their extracted residues indicated that there were many subtle influences which affected the solubility of the phosphate rock components, but a general ‘deactivation’ of phosphate rock residues on acidulation as previously suggested was not apparent. Before any particular method can be recommended as an alternative to existing one step extraction techniques it is necessary to confirm its validity through agronomic trials.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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