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  • 1
    Electronic Resource
    Electronic Resource
    Optimization of method for speciation of mercury(II), monomethylmercury cation, dimethylmercury and diethylmercury by hydride generation (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 8 (1994), S. 709-713 
    Details
    ISSN: 0268-2605
    Keywords: Hydride generation ; monomethylmercury ; dimethylmercury ; statistics ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This paper describes optimization details of an analytical method development of a hydride-generation procedure for speciation of mercury(II), monomethylmercury cation, dimethylmercury, and diethylmercury using a heated quartz furnace with an atomic absorption spectrophotometer (AAS) as a detector. Typically a new analytical method is developed in steps such as the following: (1) determining analytes individually to confirm retention times and the lack of decomposition during the procedure; (2) comparing peak areas of all analytes as a function of quartz furnace temperature to optimize atomization for AAS detection; (3) conducting factorial experiments to determine which hydride-generation reaction conditions are important in maximizing peak areas and which conditions interact with each other; (4) using the simplex optimization method to give final optimization of reaction conditions. These steps result in conditions that maximize optimized peak areas for analytes while minimizing experimental error.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aoc.590080723
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Methylation of tin(II) and lead(II) in sediment by carbanion donors (1987)
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 1 (1987), S. 115-118 
    Details
    ISSN: 0268-2605
    Keywords: Factorial experiment ; Methylcobalamin ; Model Cobalamins ; Methyltins ; Methylleads ; Methylmetals ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A factorial experimental design determined separate and combined effects of MeCoB12 (methylcobalamin) and Me2Co(N4)+ (a methylcobalamin model) on methylation of Sn(II) and Pb(II) in sediment matrices. Total methyltin yields ranged from 1.4% to 3.2%, and total methyllead yields varied from 0.037% to 0.11%. No methylmetal products occurred in the absence of Me2Co(N4)+.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aoc.590010203
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Determination of monomethylmercury cation in sediments by vacuum distillation followed by hydride derivatization and atomic fluorescence spectrometric detection (1997)
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 11 (1997), S. 761-769 
    Details
    ISSN: 0268-2605
    Keywords: methylmercury ; dimethylmercury ; mercury speciation ; estuarine sediment ; sodium borohydride derivatization ; atomic fluorescence spectrometry ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This paper presents a method capable of quantitatively separating sub-nanogram amounts of monomethylmercury cation (MeHg+) and dimethylmercury from sediments by vacuum distillation at 40 °C and 6 μm Hg pressure followed by hydride derivatization and atomic fluorescence spectrometric detection. Concentrations of MeHg+ in Great Bay Estuarine sediments ranged from 2.2 to 7.3 ng g-1 (dry weight) with a 4.7 ng g-1 average for samples taken over nine weeks of the 1996 summer. The RSD for replicate determinations of a homogenized estuarine sediment is typically less than 6%. The detection limit for the routine determinations on MeHg+ is 0.2 ng g-1 dry weight of sediment. We validated the method by determining MeHg+ concentration in reference sediment S-19, by confirming our method against an established extraction method, and by recovering 85% of 10 ng MeHgCl spiked into estuarine sediments. This paper also includes significant improvements in the hydride derivatization method for mercury compounds relative to previous work with respect to faster analysis time and lower detection limits. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
  • 4
    Electronic Resource
    Electronic Resource
    Critical review of analytical methods for determination of inorganic mercury and methylmercury compounds (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 8 (1994), S. 293-302 
    Details
    ISSN: 0268-2605
    Keywords: Analytical methods ; mercury ; monomethylmercury ; dimethylmercury ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This review describes determinations of mercury compounds under three categories: total mercury; separate determinations of inorganic mercury(II) and organomercury compounds by selective reduction; and speciation of inorganic mercury(II), monomethylmercury cation, and dimethylmercury. Topics described for each category include sample treatment, separation, detection, and limit of detection. Finally, we note that most methods would not detect dimethylmercury if it were present.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/aoc.590080404
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    Paper (German National Licenses)
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