ISSN:
1572-8862
Keywords:
Vanadate-supported rhodium complex
;
C-C coupling
;
rhodium acetylacetonato complex
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Abstract The methallyl moieties of [{(η3-C4H7)2Rh}2(V4O12)]2− couple to yield 2,5-dimethyl-1,5-hexadiene in a selective manner by the action of P(OEt),3, while the reaction of [(η 3-C4H7)2 Rh(acac)] with P(OEt)3 produces a mixture of organic compounds. The result shows that the vanadate support has a significant influence on the reactivity of organometallic complexes.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01166179
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