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  • Polymer and Materials Science  (4)
  • Flow injection analysis  (3)
  • 1
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Flow injection analysis ; Combined flow injection/HPLC ; Carbamate pesticides
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary An integrated flow injection (FI)/HPLC system for the total and individual determination of carbamate pesticides (propoxur, carbofuran and carbaryl) is proposed. The determination is based on the alkaline hydrolysis of the analytes and subsequent coupling with diazotized sulphanilic acid to yield the monitored dyes with or without a prior separation step by HPLC in a C18 column. The calibration curves obtained are linear in the μg/ml range and r.s.d. values are between 0.5 and 3.7% in all instances. Injection of the sample into the FI manifold allows the total pesticide content in the sample to be screened. The manifold thus acts as a post-column reactor/detector of the chromatograph for samples with high overall carbamate content, which are also injected into the HPLC instrument. The performance was checked with contaminated water samples.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Flow injection analysis ; Combined methods ; Transition metal ions ; Aqueous samples
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary An automatic method based on the combination of a flow injection (FI) manifold with a liquid chromatograph has been developed for the enrichment and determination of transition metal ions in water samples. Alternatively, the FI configuration can be used as a screening system for the determination of the total concentration of heavy metals. Two-parameter expressions for calibration graphs involving preconcentration time and concentration of the analytes were established for both the FIA and the integrated FIA/HPLC methods. The preconcentration time depends on the concentration level of the analytes in the samples. The method is linear in the range 2–200 ng/ml, with r.s.d. values between 1.5 and 5.0. It has been applied to the determination of copper, lead, zinc, nickel, cobalt, cadmium and manganese in synthetic water samples.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Aminopropyl-silica sorbent ; Continuous cleanup/preconcentration ; Hydroxyvitamin D3 metabolites ; Flow injection analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A new procedure for continuous cleanup and concentration of hydroxyvitamin D3 metabolites prior to their separation by HPLC and UV-detection is reported. The process is based on the use of aminopropyl-silica as solid-phase sorbent as an alternative to the use of nonpolar sorbents. The improvement thus achieved has been tested by comparing the results with those obtained using octadecyl-C18 as non-polar sorbent. The comparison has been based on the calibration graphs (linear range, detection and quantitation limits), precision and multiple standard addition method.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1040-0397
    Keywords: Continuous stripping voltammetry ; Zinc ; Cadmium ; Simultaneous ; Biological samples ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A flow-injection (FI) voltammetric-stripping method for the simultaneous determination of Cd and Zn is proposed after a systematic study of the variables affecting the method. The low determination limits, 1 × 10-9 and 5 × 10-9 M (detection limits 8 × 1010- and 2 × 10-9 M for Cd and Zn, respectively), and rsd. values, 1.57 and 5.16% for Cd and Zn, respectively, allow one to apply the method to real samples (biological tissues and reference materials) with good results. No formation of intermetallic compounds was detected.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1040-0397
    Keywords: Lyophilization ; Digestion ; Flow-injection analysis ; Anodic stripping voltammetry ; Simultaneous determination ; Copper ; Lead ; Cadmium ; Zinc ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Improvements in three main aspects of the analysis of metal traces in biological tissues are proposed, namely: (a) lyophilization of the samples both to preserve them and to favor the digestion process; (b) digestion of the lyophilized tissues using an effective and fast procedure; and (c) automatic determination of the target analytes by flow-injection analysis/anodic stripping voltammetry (FIA/ASV). After optimization of these steps, the overall procedure was successfully applied to the simultaneous determination of copper, lead, cadmium, and zinc in certified reference materials (CRMs) and fresh bovine liver samples with good results. Finally, the performance of the method was validated by a statistical study using parameters of the certification campaign of the CRMs; the results obtained being within, or close to, the confidence levels of the certification campaign.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Electroanalysis 4 (1992), S. 601-613 
    ISSN: 1040-0397
    Keywords: Electrochemical detectors ; flower injection analysis ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The state-of-the-art in the use of electrochemical detectors in unsegmented flow systems in general, and flow injection analysis (FIA) in particular, is presented. The different ways in which unsegmented flow systems can help to improve the performance and scope of electrochemical detectors (e.g., facilitating automation and miniaturization, allowing the on-line implementation of continous separation techniques and multidetermination methods) are discussed. Current trends in this context are also covered.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 34 (1997), S. 157-163 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Hip replacement implants fabricated using the ASTM F-75 alloy sometimes fail in a sudden catastrophic way. In general, fractures start at microstructural defects subjected to stress-corrosion under chemical attack by body fluids. In this paper the results of a study on the effect of casting parameters on the microstructure of ASTM F-75 are presented. The preheating mold temperature and the liquid temperature were varied between 900 and 1000°C, and 1410 and 1470°C, respectively. Optimum static strength and ductility were obtained when shrinkage microporosity and the volume fraction of M23C6 “eutectic” carbides precipitated at grain boundaries were minimized by increasing the preheating mold temperature to 1000°C and by using intermediate pouring temperatures of 1455°C. Under these casting conditions, however, the solidification rates are low, leading to large grain sizes, which, in turn, reduce the strength of the material under dynamic loading conditions. The volume fraction of the M23C6, “blocky” carbides appears to be independent of the casting conditions; however, their size and spatial distributions determine the strength of the as-cast alloys. © 1997 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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