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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 11 (1988), S. 167-172 
    ISSN: 0935-6304
    Keywords: Gas chromatography (GC) ; Capillaries ; Fused silica ; Surface properties ; Adsorption ; Aldehydes and ketones ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: By using gas chromatographic intermediate surface testing to study the surface properties of fused silica capillary tubing, the reversible adsorption of aldehydes and ketones on the fused silica surface has been observed for the first time. It is shown that this interaction can arise from the preferential interaction of carbonyl functional groups at bonded silanol sites on the surface. It is further shown that simple test mixtures containing aldehydes or ketones can be used to probe the concentration of water and bonded silanols on the surface and thus to evaluate capillary manufacturing processes and thermal and chemical surface treatments.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 11 (1988), S. 395-400 
    ISSN: 0935-6304
    Keywords: Gas chromatography (GC) ; Fused silica ; Column technology ; Surface modification ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A method has been developed for fabricating fused silica capillary columns which have specific surface properties but still retain the excellent strength, flexibility, and resilience of pure fused silica. By using the Modified Chemical Vapor Deposition process (MCVD), typically used for the production of optical fiber lightguides, inorganic dopants such as Al, Nd, Ge, and P can be introduced into the preform-tube by MCVD. Doped columns have a wide range of specific surface properties, and columns with undoped fused silica prepared by MCVD are more chemically inert and less acidic than columns prepared by conventional methods. This paper describes the method for fabricating capillaries and the initial studies to characterize them.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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