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Direct Evidence of Solvent-Peroxovanadium Clusters by Electrospray Ionization Mass Spectrometry (1998)

Bortolini, Olga ; Conte, Valeria ; Di Furia, Fulvio ; [weitere]

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 1998 (1998), S. 1193-1197

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Details

ISSN: 1434-1948

Schlagwort(e): Peroxo complexes ; Vanadium ; Mass spectrometry ; Ion-molecule reactions ; Ab initio calculations ; Chemistry ; General Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: Electrospray Ionization Mass Spectrometry (ESI-MS) measurements and ab initio calculations on [OV(O2)(H2O)m-(CH3OH)n]+ (m,n: 0-4) peroxo cations have been carried out. This experimental technique allowed the direct observation of the above mentioned species for the first time. The results obtained clearly indicate that the exchange reactions between water and methanol molecules, within the coordination sphere of monoperoxo-vanadium complexes, is a conceivable and fast process.

Materialart: Digitale Medien

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