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The Mechanism of Ozonolysis Revisited by 17O-NMR Spectroscopy (1998)

Geletneky, Christian ; Berger, Stefan

Weinheim : Wiley-Blackwell

Liebigs Annalen 1998 (1998), S. 1625-1627

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ISSN: 1434-193X

Keywords: Ozonolysis ; Mechanism ; 17O NMR ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The mechanism of ozonolysis was revisited with the use of 17O-NMR spectroscopy. In a crossover experiment with 17O-labelled benzaldehyde and the ozonides of styrene and ethylidenecyclohexane it was shown that only the ether bridge of the secondary ozonides is carrying the 17O label. This is contrary to results reported earlier and confirms the Criegee mechanism.

Type of Medium: Electronic Resource

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