ISSN:
0170-2041
Keywords:
Grandisol
;
[2 + 2]-Photocycloaddition
;
Cu(I) catalysis
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Grandisol (10) is stereoselectively synthesized in 9 steps, starting from commercially available 3-methyl-3-buten-1-ol (1). The key step of the synthesis is the Cu(I)-catalyzed [2 + 2]-photocycloaddition of 3 to 4a or 4b. Moreover, solvent effects on the endo/exo product ratio of the [2 + 2]-photocycloaddition are investigated.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jlac.199219920144
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