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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Journal of solution chemistry 6 (1977), S. 357-367 
    ISSN: 1572-8927
    Schlagwort(e): High pressure ; dielectric constants ; density ; acetonitrile ; temperature dependence ; Kirkwoodg factor
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The static dielectric constant of liquid acetonitrile is reported at 10, 25, and 40°C and at pressures up to 3 kbar. Densities of pure acetonitrile were measured where needed in order to analyze the dielectric measurements using the Kirkwood-Fröhlich equation. The Kirkwood correlation factorg K was found to be less than unity with a positive temperature but negative pressure coefficient, suggesting an increasing anticorrelation of dipoles with decreased temperature and increased pressure. Theg K factors are analyzed by a dipole pair-bonding model as outlined by Dannhauser and Flueckinger in which the lowg K values are attributed to the presence of dimers consisting of completely anticorrelated dipoles. The implication of this model on other measurements, especially MNR relaxation studies, is examined.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 2 (1979), S. 211-215 
    ISSN: 0935-6304
    Schlagwort(e): Liquid chromatography, HPLC ; Reverse phase separation of 9 antibiotics ; Down to 5 min analysis time, less than 4% repeat variation ; Precise analytical conditions given ; Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Chromatographic methods are presented for the determination of chloramphenicol, erythromycin, tyrothricin, nystatin, penicillin, streptomycin, sulphanilamides and nitrofurans, in some pharmaceutical formulations. The methods have been applied in routine analysis and are in general capable of distinguishing the main antibiotic from decomposition products and likely congeners.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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