ISSN:
1572-879X
Keywords:
Hydroformylation
;
cobalt carbonyl/tertiary phosphine system
;
1H-NMR
;
X-ray diffraction structure
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Mono- and disubstitution of HCo(CO)4 with tertiary phosphines and phosphites was studied by IR and1H-NMR spectroscopy. It was found that these substitutions proceed through phosphonium tetracarbonylcobaltate intermediates, leading to a mixture of isomers. The crystal and molecular structure of trans-HCo(CO)3[P(O-p-C6H4Ph)3] was determined by X-ray diffraction.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00767082
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