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  • 1
    Electronic Resource
    Electronic Resource
    Miscibility window for the blends of poly(styrene-co-4-vinylphenymethylphenylsilanol) with poly(n-butyl methacrylate) (1996)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 34 (1996), S. 3163-3172 
    Details
    ISSN: 0887-624X
    Keywords: miscilibilty window ; polymer blends ; hydrogen bonding ; poly(styrene-co-4-vinylphenylmethylphenylsilanol) ; FT-IR ; glass transition temperature ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polymer blends consisting of poly(styrene-co-4-vinylphenylmethylphenylsilanol) (ST-VPMPS) and poly(n-butyl methacrylate) (PBMA) have been investigated. The experimental results showed that miscible blends were formed when ST-VPMPS copolymers contained 9-56 mol % silanol functional groups. Comparison of the results with poly(styrene-co-4-vinylphenyldimethylsilanol) (ST-VPDMS)/PBMA blends revealed that the miscibility window was shifted to a higher silanol composition in the present system in which a stronger hetero-associated hydrogen bonding interaction was present. The results were discussed in terms of steric shielding and electron-withdrawing effects of the phenyl substituent bound directly to the silicon atom. © 1996 John Wiley & Sons, Inc.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1996.868
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  • 2
    Electronic Resource
    Electronic Resource
    Miscible blends through hydrogen bonding: effects on polymer properties (1994)
    New York, NY : Wiley-Blackwell
    Polymers for Advanced Technologies 5 (1994), S. 600-602 
    Details
    ISSN: 1042-7147
    Keywords: Miscible blends ; Hydrogen bonding ; Thermal oxidative stability ; Glass transition temperature ; Semi-interpenetrating polymer networks ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Miscible blends through hydrogen bonding have been intensively studied. The effects of a variety of miscible hydrogen bonded polymer blends on properties such as thermal and thermal oxidative stability, moisture sensitivity, modulus and glass transition temperature are discussed. In addition, the preparation of semi-interpenetrating polymer networks (IPNs) and studies of the effect of crosslinking on the miscibility in hydrogen bonded polymer blends are reviewed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pat.1994.220050923
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    Paper (German National Licenses)
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