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  • 1
    Electronic Resource
    Electronic Resource
    Substitutive sulfotrioxidation of branched perfluoroolefins (1992)
    Springer
    Russian chemical bulletin 41 (1992), S. 1836-1840 
    Details
    ISSN: 1573-9171
    Keywords: fluoroolefins ; perfluoroalken-2-yl fluorosulfates ; perfluoroalkenoyl fluorides
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract We have studied the insertion of SO3 into the C-F bond of perfluoroolefins under conditions of electrophilic catalysis. It was shown that sufficiently high allylic mobility of the fluorine atoms is only preserved when in the allylic triad, in addition to the substituted fluorine; also not less than three fluorine atoms are present in the α and γ positions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00863819
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Conjugated Additions in Hydrogen Fluoride (1969)
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 8 (1969), S. 349-356 
    Details
    ISSN: 0570-0833
    Keywords: Hydrogen fluoride ; Solvents ; Fluorination ; Fluorine ; Addition ; Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Fluorine and another substituent can be added in a single step to compounds having CC double bonds in anhydrous hydrogen fluoride. It is possible in this way to obtain e.g. α-fluorinated β-halogeno, β-alkyl, β-nitro, and β-amino compounds, and also (in some cases by secondary reactions) fluorinated ethers, alcohols, esters, and carboxylic acids, β-fluoro alcohols can be obtained by conjugated “hypofluorination” in the presence of oxenium ions.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/anie.196903491
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    Paper (German National Licenses)
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