ISSN:
1572-8862
Keywords:
Dynamic behavior
;
17O NMR
;
vanadium oxide cluster
;
cyclooctadienerhodium(I) fragment
;
intramolecular rearrangement
Source:
Springer Online Journal Archives 1860-2000
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Abstract Variable-temperature17O NMR together with51V and103Rh NMR studies on newly prepared vanadium oxide-supported organorhodium(I) fragment(s), [(RhCOD) n (V4O12)](4−n)− (n = 1, 2; COD =η 4-1,5-cyclooctadiene) indicate that intramolecular rearrangements of RhCOD fragment(s) on a vanadium oxide surface occur in solution.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01171386
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