ISSN:
1572-8927
Keywords:
Activity coefficient
;
electrolytes
;
mixed
;
Harned coefficients
;
hydrochloric acid
;
mixed electrolyte solutions
;
sodium chloride
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Electromotive-force measurements of the cell $$Pt;H_2 \left( {g,1{\text{ }}atm} \right)|HCl\left( {{\text{m}}_A } \right),NaCl\left( {{\text{m}}_B } \right)|AgCl;Ag$$ have been made at temperatures between 5 and 45°C at values ofm A+m B of 0.1, 0.3809, 0.6729, and 0.8720 mole-kg−1. The activity coefficients of HCl in HCl/NaCl mixtures and the Harned coefficients α12 have been obtained. The change of α12 with total molality is consistent with the existence of binary interactions between H+ and Na+ ions. The linear variation of the relative partial molal heat content with the fraction of NaCl in the mixture suggests that an analog of the Harned rule exists for this thermodynamic quantity.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00645511
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