ISSN:
0009-2940
Keywords:
Imido ligands
;
Amido ligands
;
Niobium complexes
;
Tantalum complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Multiple Bonds between Main-Group Elements and Transition Metals, CII[1]. - Volatile MN4 Metal Complexes of Niobium and Tantalum Containing Dimethylsilyl SubstituentsNiobium and tantalum complexes 4a and 4b of formula (Me2SiH)N=M[N(SiHMe2)2]3 (a: M=Nb; b: M=Ta) are formed from lithium bis(dimethylsilyl)amide and either MOCl3 (2a,b) or MCl5 (3a,b). No β-hydrogen decomposition of these compounds occurs under normal conditions.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921250119
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