ISSN:
0009-2940
Keywords:
Carbyne complexes
;
Carbene complexes
;
3H-1,2,3,4-Triazametalloles
;
Molybdenum complexes
;
Tungsten complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Synthesis of 3H-1,2,3,4-Triazametallole Complexes by the Addition of Methyl Azidoformate to the Metal-Carbon Triple Bond of Cyclopentadienyl-Substituted Carbyne Complexes of Molybdenum and TungstenN3CO2Me attacks the electron-rich metal-carbon triple bond in C5H5(CO)2 - n (PMe3)nM≡CR (M = Mo, W; R = Ph, Tol; n = 0, 1) (1) to provide neutral 3H-1,2,3,4-Triazametallole complexes 2.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921250710
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