ISSN:
0044-2313
Keywords:
Bis(thiophenolato)metal complexes
;
preparation
;
structure
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Preparation and Structures of Monomeric Bis(thiophenolato)metal(II) ComplexesSodium-2,4,6-tris(trifluoromethyl)thiophenolate (NaSRf) reacts with MCl2 (M = Zn, Pb) in the molar ratio of 2:1 to form the bis(thiophenolato)metal(II)complexes bis[2,4,6-tris(trifluoromethyl)thiophenolato]zinc 1 and bis[2,4,6-tris(trifluoromethyl)thiophenolato]lead 2. Reaction of Mn[N(SiMe3)2]2· THF with two equivalents of 2,4,6-tris(trifluoromethyl)thiophenol (RfSH) forms Mn(SRf)2 · THF 3. All compounds crystallize as THF adducts. The structures of Zn(SRf)2 · 2THF 1a, Pb(SRf)2 · THF 2a and Mn(SRf)2 · 2THF 3a are discussed.
Notes:
Natrium-2,4,6-tris(trifluormethyl)thiophenolat(NaSRf) reagiert mit MCl2 (M = Zn, Pb) im Molverhältnis 2 : 1 zu den Bis(thiophenolato)metall(II)-Komplexen Bis[2,4,6-tris(trifluormethyl)thiophenolato]-zink 1 und Bis[2,4,6-tris(trifluormethyl)thiophenolato]blei 2. Bei der Reaktion von Mn[N(SiMe3)2]2· THF mit zwei äquivalenten 2,4,6-Tris(trifluormethyl)thiophenol (RfSH) wird Mn(SRf)2· THF 3 erhalten. Alle Verbindungen kristallisieren als THF-Addukte. Die Kristallstrukturen von Zn(SRf)2· 2 THF 1a, Pb(SRf)2· THF 2a und Mn(SRf)2· 2THF 3a werden diskutiert.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19926100127
Permalink
