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Vibrational interaction potentials (1983)

Bergen, Y. ; Bergen, R. ; Linder, B.

Springer

Theoretical chemistry accounts 63 (1983), S. 317-322

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ISSN: 1432-2234

Keywords: Van der Waals ; Vibrational ; Intermolecular ; Interaction ; Potential

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract An expression is derived for the interaction potential arising from the correlative vibrational motion of fluctuating dipolar diatomic molecules, using as model the Morse oscillator. The theory is applied to two interacting NaCl molecules. The vibrational dipole-dipole coefficient,C 6, is strongly temperature dependent with a value at room temperature of 3.788 × 10−62 erg cm6.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01151609

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