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  • Irreversible thermodynamics  (1)
  • Non-linearviscoelasticity  (1)
  • flux relaxation  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 25 (1986), S. 207-213 
    ISSN: 1435-1528
    Keywords: Irreversible thermodynamics ; constitutive equation ; Maxwell model ; viscoelasticity ; auto-correlation function
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract The underlying thermodynamic aspects of linear viscoelasticity are discussed. In particular, from the Extended Irreversible Thermodynamics theory we systematically derive the Maxwell model exhibiting its compatibility with thermo-dynamics and assessing its conditions of validity. We also calculate the equilibrium transverse velocity auto-correlation function and the frequency dependent shear viscosity. Nonlinear generalizations of our model are suggested and the possible role of extended thermodynamics in selecting constitutive equations is also discussed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Rheologica acta 28 (1989), S. 233-237 
    ISSN: 1435-1528
    Keywords: Non-linearviscoelasticity ; Jeffreys model ; non-isothermal effects ; Rayleigh problem ; irreversiblethermodynamics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract We use a thermodynamic approach to non-linear viscoelasticity which predicts a coupling between the stress tensor and the heat flux, to generalize the Rayleigh problem for an Oldroyd B model of a fluid. For a special choice of the external temperature gradient, we show that thermal effects do alter the hydrodynamic velocity field as well as the first and second normal stress differences. These quantities depend on renormalized parameters wich explicitly depend on temperature and on the strength of the coupling. In particular we find that in contrast to the isothermal situation, the second normal stress difference does not vanish. The possibility of an experimental verification of our theoretical predictions is also mentioned.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 37 (1984), S. 465-484 
    ISSN: 1572-9613
    Keywords: Extended irreversible thermodynamics ; kinetic theory ; fluctuations ; memory functions ; projection operators ; flux relaxation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A theory of macroscopic systems which takes as independent variables the slow (conserved) ones plus the fast dissipative fluxes is carefully analyzed at three levels of description: macroscopic (thermodynamic), microscopic (projection operators) and mesoscopic (fluctuation theory). Such a description is compared with the memory function approach based only on the conserved variables. We find that the first theory is richer and wider than the second one, and some misunderstandings in this connection are clarified and discussed.
    Type of Medium: Electronic Resource
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