ISSN:
1572-8927
Keywords:
KCl
;
KBr
;
KClO3
;
KBrO3
;
KlO3
;
KClO4
;
KlO4
;
D2O
;
conductance
;
transference numbers
;
aqueous solutions
;
structural effects
;
solvent isotope effects
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Precise limiting ionic conductance data are reported for the first time for the alkali metal and tetraalkylammonium ions in D2O at 10°C as well as similar data for the halate and perhalate ions in D2O and H2O at 10 and 25°C. Precise transference numbers by the moving-boundary method are also reported for KBr in D2O at 10°C and, as a check on earlier work, for KCl in D2O at 25°C. In general, the structural properties of the ions, as reflected in the temperature coefficient of the limiting ionic conductances, are enhanced in D2O compared to H2O, although the differences are often small.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00650531
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