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  • Key words: Hydrogen, DDT, Induction distance, Initiation, High pressure  (1)
  • Key words: Shock-wave focusing, Detonation initiation  (1)
  • Key words:Shock tube experiments, Formation of molecules, Microwave absorption technique  (1)
Materialart
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  • 1
    ISSN: 1432-2153
    Schlagwort(e): Key words:Shock tube experiments, Formation of molecules, Microwave absorption technique
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik , Technik allgemein
    Notizen: Abstract. The paper describes experimental investigations in a shock tube concerning the formation of new molecules using He as a driver gas and a mixture of Kr, CH $_4$ and NH $_3$ as driven gas, where Kr serves as diluant. By microwave absorption technique it was possible to detect HCN, CH $_2$ O and CH $_3$ NH $_2$ as reaction products. Obviously, these molecules were formed in the plasma behind the shock wave. In addition, the “swan bands” of C $_2$ have been observed with optical methods.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Shock waves 10 (2000), S. 205-215 
    ISSN: 1432-2153
    Schlagwort(e): Key words: Shock-wave focusing, Detonation initiation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik , Technik allgemein
    Notizen: Abstract. From practical and theoretical standpoints, the initiation of combustion in gaseous media due to the shock waves focusing process at various reflectors is a subject of much current interest. The complex gas flowfield coupled with chemical kinetics provides a wide spectrum of possible regimes of combustion, such as fast flames, deflagration, detonation etc. Shock wave reflection at concave surfaces or wedges causes converging of the flow and produces local zones with extremely high pressures and temperatures. The present work deals with the initiation of detonation due to shock waves focusing at parabolic and wedge reflectors. Particular attention has been given to the determination of the critical values of the incident shock wave (ISW) Mach number, parameters of the combustible mixture, and geometrical sizes of reflector at which different combustion regimes could be generated.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    ISSN: 1432-2153
    Schlagwort(e): Key words: Hydrogen, DDT, Induction distance, Initiation, High pressure
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik , Technik allgemein
    Notizen: Abstract. In this paper the formation of detonation in H $_2$ -O $_2$ /He/Ar mixtures at elevated initial pressures was investigated in an initiation tube for a detonation driver with an exploding wire as the ignition source. In most experiments the detonation wave was formed by a DDT process in which a reactive shock wave accelerates behind the leading shock wave and eventually leads to the onset of detonation. The onset position was found to be at the leading shock wave or behind it. Only in very sensitive mixtures at high initial pressure the direct initiation of detonation was observed. The influence of ignition energy, initial pressure and composition on the detonation induction distance was determined. The results show that the detonation induction distance increases with the decrease of ignition energy and initial pressure and with the increase of the mole fraction of helium or argon. With the same mole fraction, argon increases the induction distance more than helium. In the facility utilized the DDT upper and lower limits of hydrogen in H $_2$ -O $_2$ mixtures are in the ranges from 36 to 40 % and from 78 to 82 %, respectively, and the upper limits for helium and argon in stoichiometric H $_2$ -O $_2$ mixtures are 40 % and 36 %, respectively. High pressure peaks generated by the DDT process were measured, especially in mixtures near the DDT limits. Statistical results show that such peak pressures can be up to 6 times of the CJ-pressures.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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