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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Physics and chemistry of minerals 27 (2000), S. 203-212 
    ISSN: 1432-2021
    Keywords: Key words Kinetics ; Feldspar ; Fluctuations ; BaAl2Ge2O8 ; Partial conservation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Abstract The kinetics of monodomain order-disorder processes in monoclinic (I2/c) BaAl2Ge2O8-feldspar have been investigated by X-ray powder diffraction, Hard Mode IR Spectroscopy, and TEM darkfield imaging on quenched samples. Compared to the behaviour predicted by the TDGL approximation ordering kinetics observed at low temperatures slow down significantly when equilibrium is approached. Such a delay is not observed in disordering experiments starting from essentially ordered cation distributions. The deviation from TDGL behaviour is interpreted in terms of partial order parameter conservation in a non-uniformly ordered phase. Modifications to the uniform TDGL rate equation are tested against the available data. An activation energy of 352 ± 28 kJ/mol is obtained for Al,Ge ordering. The mixing coefficient ξc 2/ξ2, which describes the degree of order parameter conservation, is obtained as a function of temperature. While this coefficient vanishes in the vicinity of the transformation temperature T tr, it saturates towards a level of ξc 2/ξ2≈0.4 for T→0. ξ c 2/ξ2 determines the kinetic stability of ordered clusters quenched from T≈T tr.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of superconductivity 11 (1998), S. 755-768 
    ISSN: 1572-9605
    Keywords: Optical properties ; electron–phonon interaction ; high-T c superconductors
    Source: Springer Online Journal Archives 1860-2000
    Topics: Electrical Engineering, Measurement and Control Technology , Physics
    Notes: Abstract Observed optical reflectivity in the infrared spectral region is compared with theoretical predictions in a strongly coupled electron–phonon system. Starting from a Fröhlich Hamiltonian, the spectral functions and their temperature dependence are derived. A full analysis including vertex corrections leads to an expression for the optical conductivity σ(ω) that can be formulated in terms of the well-known optical conductivity for a quasi-isotropic system without vertex corrections. A numerical comparison between the full result and the so-called extended Drude formula, its weak coupling expansion, shows little difference over a wide range of coupling constants. Normal-state optical spectra for the high-T c superconductors YBa2Cu3O7 and La2 − x Sr x CuO4 at optimal doping are compared with the results of model calculations. Taking the plasma frequency and ∈∞ from band structure calculations, the model has only one free parameter, the electron–phonon coupling constant λ. In both materials the overall behavior of the reflectivity can be well accounted for over a wide frequency range. Systematic differences exist only in the mid-infrared region. They become more pronounced with increasing frequency, which indicates that a detailed model for the optical response should include temperature-dependent mid-infrared bands.
    Type of Medium: Electronic Resource
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