ISSN:
0044-2313
Keywords:
Lead
;
meso-Oxolane-3,4-diolate(2-)
;
Anhydroerythritol
;
Coordination Polymer
;
Crystal Structure
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Polyol Metal Complexes. X. Lead(II) meso-Oxolane-3,4-diolate(2-) Monohydrate - a Polymeric Lead Alkoxide from Aqueous SolutionIn the colourless crystals of Pb(C4H6O3) · H2O (P21/c, a = 569.8(3), b = 607.6(4), c = 1856.9(9) pm, β = 89.90(4)°, V = 642.9(6) · 106 pm3, Z = 4), lead(II)- and meso-oxolane-3,4-diolate(2-) ions form a one-dimensional coordination polymer; PbII is coordinated with four bridging alkoxide O-atoms (mean distance: 234.5 pm); some 100 pm more distant two μ-O-atoms of water molecules coordinate the lead ion.
Notes:
Blei(II)- und meso-Oxolan-3,4-diolat(2-)-Ionen bauen in den farblosen Kristallen von Pb(C4H6O3) · H2O (P21/c, a = 569,8(3), b = 607,6(4), c = 1856,9(9) pm, β = 89,90(4)°, V = 642,9(6) · 106 pm3, Z = 4) ein kettenförmiges Koordinationspolymer auf, in dem PbII von vier verbrückenden Alkoxid-O-Atomen koordiniert ist (mittlerer Abstand: 234,5 pm); ungefähr 100 pm weiter entfernt koordinieren zwei ebenfalls verbrückende Wasser-O-Atome.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19956210106
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