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  • correlation function decay  (2)
  • Long-range order  (1)
  • RISM equation  (1)
  • Surface phase transitions  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 17 (1977), S. 47-60 
    ISSN: 1572-9613
    Keywords: Surface phase transitions ; adsorption isotherms ; dense fluids
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We derive adsorption isotherms for an adsorbate of hard-sphere particles with “sticky” interactions at any fluid density being adsorbed onto a plane, “sticky” surface. The theory is based on the Percus-Yevick theory for bulk fluids and explicitly includes the equilibrium between the adsorbed fluid and the bulk adsorbate. The theory predicts a surface condensation at low temperatures and low bulk densities in good agreement with surface condensations found in experimental studies of adsorption of gases onto graphite. An approximate law of corresponding states for these transitions is developed. At higher bulk densities and room temperatures, the adsorption isotherms can show a maximum, in accord with recent experimental work.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 24 (1981), S. 607-616 
    ISSN: 1572-9613
    Keywords: RISM equation ; diatomic ; correlation functions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Using the solution of the RISM equation for diatomic symmetric molecules outlined in a previous paper, the site-site radial distribution function (RDF) is calculated and compared with the Monte Carlo results and the numerical RDF of Lowden and Chandler. The RDF calculated here and the numerical RDF of Lowden and Chandler agree well at intermediate and high densities. At low density, however, both have systematic errors. The agreement between the RDF calculated here and the Monte Carlo results suggests that a simplified formulation of the RISM solution may serve well as a reference system in a perturbation theory for diatomic fluids.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 50 (1988), S. 813-838 
    ISSN: 1572-9613
    Keywords: Spherical model ; Coulombic systems ; correlation function decay ; Stillinger-Lovett relations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We consider simple cubic lattice systemsΛ ind dimensions with a continuous real charge variableq(n) at each lattice siten. These variables are subject t'o a mean spherical constraint forcing 〈∑n∈Λ q 2(n)〉=‖Λ‖Q 2, where ‖Λ‖ is the number of lattice sites inΛ andQ is an elementary charge. The energy of the charges comes from interactions with an electrostatic potential, which is the solution of a symmetric second-difference Poisson equation on the lattice. Two cases are considered, both of which allow the inclusion of the effects of a fixed, constant, external electric field. On the latticeΛ 1=[1,N]⊗d , a Neumann condition is imposed at the surface of the lattice. The latticeΛ 2=[1,N]⊗ [−M,M]⊗(d−1) is periodic in each direction ranging over [−M, M] and has a Dirichlet condition imposed at the other two surfaces. OnΛ 2 a finite electric field may be applied, while onΛ 2 a finite potential difference may be applied across the lattice. The models are exactly solvable. We study the distribution functions on each system and show that they satisfy appropriate forms of the first two Stillinger-Lovett moment conditions. The two charge distribution functions show screening behavior at high temperature and extreme short range at an intermediate temperatureT 0(d), and oscillate as they decay to zero forT〈T 0(d). Because of the continuous nature of the charge variables, there is no Kosterlitz-Thouless transition in two dimensions. In three dimensions the change in the decay behavior of the distribution functions atT〈T 0(d) is precursor to a phase transition to a charge ordered state.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 33 (1983), S. 13-22 
    ISSN: 1572-9613
    Keywords: Long-range order ; semiperiodic boundary conditions ; two-dimensional-one-component plasma
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The one-component two-dimensional plasma is studied in a strip of finite width, replicated periodically parallel to the long axis of the strip. Exact results for the one- and two-particle distribution functions are found at coupling Γ=q 2/kT =2. The system is inhomogeneous: the one- and two-particle distribution functions show long-range order.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 55 (1989), S. 127-139 
    ISSN: 1572-9613
    Keywords: Spherical model ; Coulombic systems ; correlation function decay ; surface properties
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Studies of the mean spherical model with Coulomb interactions are continued, by considering a system on ad-dimensional lattice which is periodic ind−1 dimensions and has a free surface in the remaining dimension. It is shown explicitly that correlations along the free surface decay asy −d ind dimensions and show that the surface properties of this model are those expected for a charged system in its plasma phase.
    Type of Medium: Electronic Resource
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