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Digitale Medien

Crystal and molecular structure of aquabis(2,2′-bipyridine)nitratomanganese(II) nitrate monohydrate (1995)

Chen, Xiao-Ming ; Huang, Xiao-Ying ; Xu, Yong-Jin ; [weitere]

Springer

Journal of chemical crystallography 25 (1995), S. 605-607

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Details

ISSN: 1572-8854

Schlagwort(e): Manganese(II) nitrate ; 2,2′-bipyridine

Quelle: Springer Online Journal Archives 1860-2000

Thema: Geologie und Paläontologie , Physik

Notizen: Abstract A new monomeric manganese(II) nitrate complex with 2,2′-bipyridine (bpy), [Mn(bpy)2(NO3)(H2O)](NO3)·H2O, has been prepared and characterized by X-ray crystallography. The complex crystallizes in the triclinic space group $$P\bar 1$$ witha=9.721(3),b=14.691(5),c=8.578(3) Å, α=106.79(3), β=96.05(3), γ=82.55(3)°,V=1159.9 Å3 andZ=2. The structure comprises discrete cation [Mn(bpy)2(NO3)(H2O)]+ in which the metal atom is coordinated by a pair of bidentate bpy ligands [Mn−N=2.261(4)−2.299(4) Å], a unidentate nitrato [Mn−O=2.284(4) Å] and aqua [Mn−O=2.160(3) Å] ligands in a highly distorted octahedral arrangement.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF01667032

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