ISSN:
1572-8854
Keywords:
Manganese(II) nitrate
;
2,2′-bipyridine
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract A new monomeric manganese(II) nitrate complex with 2,2′-bipyridine (bpy), [Mn(bpy)2(NO3)(H2O)](NO3)·H2O, has been prepared and characterized by X-ray crystallography. The complex crystallizes in the triclinic space group $$P\bar 1$$ witha=9.721(3),b=14.691(5),c=8.578(3) Å, α=106.79(3), β=96.05(3), γ=82.55(3)°,V=1159.9 Å3 andZ=2. The structure comprises discrete cation [Mn(bpy)2(NO3)(H2O)]+ in which the metal atom is coordinated by a pair of bidentate bpy ligands [Mn−N=2.261(4)−2.299(4) Å], a unidentate nitrato [Mn−O=2.284(4) Å] and aqua [Mn−O=2.160(3) Å] ligands in a highly distorted octahedral arrangement.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01667032
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