ISSN:
1612-1112
Keywords:
Gas chromatography
;
Mass spectrometry
;
Azines
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary We have studied the gas chromatographic behaviour of several 3-methyl-2-benzothiazolone-azines. In HPLC analysis all the unsymmetrical azines show double peaks, whereas in HRGC analysis only some of these compounds show the two peaks corresponding to the Z (syn) and E (anti) isomers. By means GC/MS analysis the mass spectrum of each azine was recorded. We have assigned the E and Z configurations to the first and second gas chromtographic peaks on the basis of the ratio between the relative abundances of the two most significant framment ions at m/z 163 and 164.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02258985
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