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  • 1
    Electronic Resource
    Electronic Resource
    Stabilitäten von As(V) in Chlorokomplexen (1979)
    Springer
    Monatshefte für Chemie 110 (1979), S. 799-804 
    Details
    ISSN: 1434-4475
    Keywords: AsCl4SbCl6 ; Melt ; PCl4AsCl6 ; PCl4SbCl6 ; Raman spectra
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The temperature dependent behaviour of PCl4AsCl6, PCl4SbCl6 and AsCl4SbCl6 has been investigated byRaman spectroscopy. The As(V) containing complexes decompose into homogeneous molecular melts consisting of AsCl3, Cl2 and PCl5, respectively. In PCl4SbCl6 PCl4 + and SbCl6 − complex ions were found in the solid as well as in the molten state.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00906673
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Ramanspektroskopische Untersuchungen an PCl5 II. Das System PCl5—ZrCl4 (1980)
    Springer
    Monatshefte für Chemie 111 (1980), S. 21-27 
    Details
    ISSN: 1434-4475
    Keywords: Melt ; PCl5−ZrCl4 ; Raman spectra ; Solid
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Raman spectra of some solid and molten PCl5−ZrCl4 mixtures have been recorded. ZrCl6 2− complex ions accompanied by at least one more chlorozirconate species are present in the solid as well as in the melt. The newRaman frequencies are attributed to ZrCl5 −, which fundamentals are given and assignment is proposed to be analogous to TiCl5 −. The presence of ZrCl6 2− and ZrCl5 − can be explained by the equilibrium ZrCl6 2−+PCl4 +⇌ZrCl5 −+PCl5.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00938713
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
    Fulltext
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