ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The syntheses of optically active t-butyl 2-(p-tolylsulfinyl)propionate and -butyrate (2a and 2b, respectively) are described, and it is shown that aldol-type condensation of the corresponding enolates is limited by steric hindrance. Optically active (2a) reacted, however, in high yield with aliphatic aldehydes and lead to 80% of asymmetric induction.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19820650533
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