ISSN:
0044-2313
Keywords:
Nickel complexes
;
nitrile complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Tris(triphenylphosphane)nickel(0) Complexes with Nitrile Ligands.Synthesis, properties and reaction behaviour of (Ph3P)3Ni(η1-NCR) (R = PhCH2, 2-MeC6H4, Me3Si) complexes as well as the X-ray structure of (Ph3P)3Ni(η1-NCSiMe3) are described. With NC(CH2)nBr (n = 1, 2) instead of the analogous nitrile complexes (Ph3P)2NiBr2 and CH3CN or C2H5CN respectively are formed.
Notes:
Synthese, Eigenschaften und Reaktionen der Komplexe (Ph3P)3Ni(η1-NCR) (R = PhCH2, 2-MeC6H4, Me3Si) sowie die Kristallstruktur von (Ph3P)3Ni(η1-NCSiMe3) werden beschrieben. Mit NC(CH2)nBr (n = 1, 2) entstehen nicht die analogen Nitril-Komplexe sondern (Ph3P)2NiBr2 und CH3CN bzw. C2H5CN.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19936191029
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