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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of paleolimnology 14 (1995), S. 337-354 
    ISSN: 1573-0417
    Keywords: pollen ; palaeoecology ; paleoclimate ; glacial ; interglacial ; DCA ; North America
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Geosciences
    Notes: Abstract Raymond Basin and Bald Knob Basin, Montgomery County, Illinois, formed as kettles during Illinoian time. Fossil pollen from these basins provides information on vegetation and climate during the last glacial-interglacial cycle. The pollen profile at Raymond Basin contains an expanded Sangamonian section and an early Wisconsinan section, but both are missing the late Wisconsinan. The ages for the following pollen zones are estimated by correlation with the deep-sea δ18O record. In the late Illinoian,Picea-Pinus pollen zone 1, dating from about 150–130 ka, represents an apparently closed boreal coniferous forest indicating a cold late-glacial climate. The Sangamonian includes three major pollen zones ranging from about 130–75 ka. The early Sangamonian is represented byQuercus-Ulmus-Carya-Fagus dominance in zone 2, indicating vegetation comparable to the modern deciduous forest and climate that was warm and moist. The middle Sangamonian in zone 3, which is characterized byAmbrosia-Poaceae-Cupressaceae-Quercus pollen, suggests a savanna vegetation and a warm, dry climate. The late Sangamonian is subdivided into aQuercus-Ulmus-Carya subzone (4a) that indicates a mesic forest and greater precipitation; aQuercus-Ambrosia subzone (4b) that suggests drier climate and savanna conditions; and aQuercus-Liquidambar-Carya subzone (4c), containing the ‘southeastern forest’ element,Liquidambar, suggesting the peak in warmth and moisture. The early Wisconsinan is represented by a transitionalPicea-Chenopodiineae zone (5). This unusual assemblage suggests a cool prairie-like vegetation, perhaps with scatteredPicea trees at the end of that depositional interval. The Middle Wisconsinan is marked by the return of high percentages ofPicea andPinus pollen in zone 6. The latest pollen zone (7) is dominated by Chenopodiineae pollen and is absent at Raymond Basin. It is most likely Holocene in age, and probably represents prairie conditions and warm, dry climate. Apparent surface-temperature and apparent effective-moisture curves were derived from the first detrended correspondence analysis (DCA) axis of the pollen data. The first axis correlates well with the normalized deep-sea δ18O curve of sea surface temperature, and the second is controlled mainly by precipitation. The interglacial vegetation differs from that predicted by models driven by orbitally-induced insolation curves.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The core-shell grafting copolymer of α-methyl styrene-methyl acrylate on poly(butyl acrylate) was synthesized. The particle morphology of latex and core-shell grafting polymerization was investigated as a function of: (a) reaction temperature; (b) initiator concentration used in the secondary polymerization; (c) monomer to polymer ratio; (d) emulsifier concentration. The compatibility of this copolymer with poly(vinyl chloride) (PVC) was determined by the method of solubility parameter and scanning electron microscopy. The rheological behavior of the blend of this copolymer with PVC was investigated. The mechanical properties of the blend were determined. The results show that this copolymer can be used as processing aid for PVC. © 1994 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Polymers for Advanced Technologies 7 (1996), S. 701-703 
    ISSN: 1042-7147
    Keywords: bifunctional catalyst composition ; propylene carbonate ; dialkyl carbonate ; carbon dioxide ; poly(ethylene glycol) ; alcohols ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Poly(ethylene glycol)-potassium iodide complexes were found to have high catalytic activities in the esterification of propylene oxide and carbon dioxide under smooth experimental conditions. Furthermore, the complexes were combined with sodium methoxide to form bifunctional catalyst compositions sequentially for the above esterification, as well as the transesterification of the propylene carbonate formed in situ with some aliphatic alcohols, such as methanol, ethanol, propanol and butanol. It was found that the compositions were very effective, giving corresponding dialkyl carbonate, propylene carbonate and propylene glycol. It was noticed that the resulting dialkyl carbonate from n-butanol was diisobutyl carbonate, instead of di-n-butyl carbonate.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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