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  • 1
    Electronic Resource
    Electronic Resource
    Oxidation of Triphenylphosphine by Vanadium Oxytrichloride (2000)
    Springer
    Reaction kinetics and catalysis letters 70 (2000), S. 105-112 
    Details
    ISSN: 1588-2837
    Keywords: Oxidation ; triphenylphosphine ; vanadium oxytrichloride ; solvent effect ; mechanism
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A kinetic study on triphenylphosphine oxidation with VOCl3 was carried out in CCl4 and THF. The different mechanisms were elucidated; oxygen was activated dissociatively on solid vanadium complex in CCl4, while oxygen was coordinated molecularly on soluble vanadium complex in THF.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1010314800363
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