ISSN:
0749-1581
Keywords:
2D NMR
;
13C, 1H inverse correlation
;
13C, 19F inverse correlation
;
HMQC
;
P.E. COSY
;
NOESY
;
ROESY
;
Selective INEPT
;
Palladium complexes
;
Chelating ligands
;
Molecular modelling
;
AM1
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A series of (σ-π)palladium complexes derived from cyclooctadiene were investigated by 1H, 13C and 19F NMR. The stereochemical assignment was based on intramolecular NOEs in conjunction with molecular modelling and semi-empirical methods, and confirmed by interligand NOEs in nitrogen chelate complexes derived from the title compounds. The nitrogen chelating ligands are involved in a rotation with respect to the ligand-palladium axis.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260311014
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