ISSN:
1572-9567
Keywords:
alkyl acetate
;
chloromethane
;
Gibbs energy of activation
;
hexane
;
liquid mixtures
;
molecular interactions
;
tetrachloromethane
;
trichloromethane
;
viscosity
Source:
Springer Online Journal Archives 1860-2000
Topics:
Physics
Notes:
Abstract The viscosity η for binary mixtures of methyl acetate (MA), ethyl acetate (EA), n-amyl acetate (nAA), isoamyl acetate (iAA), decyl acetate (DeA), and dodecyl acetate (DoA) with hexane and of MA, EA, nAA, and iAA with tetrachloromethane and trichloromethane has been measured at 303.15 K over the entire range of composition. The viscosity data have been correlated with the equations of Grunberg and Nissan; Hind, McLaughlin, and Ubbelohde; Tamura and Kurata; Katti and Chaudhri; McAllister; Heric and Brewer; and Auslaender. The viscosity deviations Δη and excess Gibbs energy of activation ΔG*E of viscous flow based on Eyring's theory have been calculated. The results have been analyzed in terms of disruption of dipolar association of alkyl acetate and molecular interaction between alkyl acetate and chloromethane.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1021441122016
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