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  • PP  (1)
  • kinetic and properties  (1)
  • mechanical properties  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Radiation-induced graft polymerization of acrylic acid onto fluorinated polymers. I. Kinetic study on the grafting onto poly(tetrafluoroethylene-ethylene) copolymer (1992)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 30 (1992), S. 1969-1976 
    Details
    ISSN: 0887-624X
    Keywords: radiation grafting ; kinetic and properties ; acrylic acid and fluoro polymer ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Direct radiation-induced grafting of aqueous acrylic acid (AAc) onto poly(tetrafluoroethylene-ethylene) (ET) film has been studied. The effect of grafting conditions such as monomer concentration, exposure dose, dose rate, and film thickness on the grafting yield was investigated. The dependence of the grafting rate on monomer concentration was found to be 1.2 order. The dependence of the grafting rate on dose rate was found to be 0.6 order regardless of the film thickness. The relationship between the grafting rate and film thickness gave a negative first-order dependence. The results suggest that the grafting process is mainly controlled by monomer diffusion, and it was concluded that this grafting system proceeded by the front mechanism. The swelling behavior increases linearly with degree of grafting. The electrical conductivity and mechanical properties for the trunk and grafted polymer were investigated at different irradiation doses in air and under vacuum irradiations. © 1992 John Wiley & Sons, Inc.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1992.080300920
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  • 2
    Electronic Resource
    Electronic Resource
    Investigation of radiation grafting of vinyl acetate onto (tetrafluoroethylene-perfluorovinyl ether) copolymer films (1994)
    New York, NY [u.a.] : Wiley-Blackwell
    Polymer International 33 (1994), S. 285-291 
    Details
    ISSN: 0959-8103
    Keywords: radiation grafting ; vinyl acetate ; fluoropolymer ; DTA ; mechanical properties ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A study has been made of radiation-induced grafting of vinyl acetate (VAc) on to (tetrafluoroethylene-perfluorovinyl ether) copolymer (PFA). Effects of grafting conditions such as inhibitor and monomer concentrations and irradiation dose on the grafting yield were investigated. In this grafting system, ammonium ferrous sulphate (Mohr′s salt) was added to the monomer-solvent mixture to minimize the homopolymerization of VAc and the most suitable concentration was found to be 2.0 wt%. It was found that the dependence of the initial grafting rate on monomer concentration is of the order 1.5. The degree of grafting tends to level off at high irradiation doses due to the recombination of formed free radicals without initiating graft polymerization. Some properties of the prepared graft copolymer such as swelling behaviour, electrical conductivity, thermal and mechanical properties were also investigated. The electrical conductivity was improved by hydrolysis of poly(vinyl acetate) in the grafted chains to their respective vinyl alcohols. The tensile properties were improved by grafting; however, the elongation percent decreased. The DTA data showed thermal stability of such graft copolymers for temperatures up to 300°C, but stability decreased at higher temperatures.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pi.1994.210330308
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  • 3
    Electronic Resource
    Electronic Resource
    Preparation and thermal characterization of graft copolymer obtained by radiation grafting of individual and binary monomer systems (1995)
    New York, NY [u.a.] : Wiley-Blackwell
    Polymer International 36 (1995), S. 47-56 
    Details
    ISSN: 0959-8103
    Keywords: graft copolymerization ; radiation ; PP ; vinyl acetate ; N-vinylpyrrolidone ; DSC ; properties ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Graft copolymers were obtained by radiation-induced grafting of vinyl acetate (VAc) and N-vinylpyrrolidone (NVP) individually and in binary mixture on to polypropylene (PP) films. The effect of some grafting conditions on the grafting yield was determined. The addition of Cu2Cl2 as inhibitor to the reaction medium inhibited the homopolymerization of the comonomer. The grafting process was remarkably enhanced by using dioxan as a diluent compared with other solvents used. The addition of some inorganic salts has a great influence on the individual grafting of both monomers. The gel percent in the graft copolymer was determined; it increased as the grafting yield increased. The swelling behaviour and electrical conductivity for the grafted films slightly increased by grafting. The changes in thermal parameters such as glass transition (Tg), melting (Tm) and recrystallization (Trc) temperatures and heats of melting (ΔHm) and recrystallization (ΔHrc) of the graft copolymers were also followed by differential scanning calorimetry (DSC). These thermal parameters of PP were varied by grafting with VAc and NVP and depend on the graft yield, which reflects the change in its crystalline domains and formation of crosslinks in the graft chains. The heat of recrystallization of the graft copolymer by cooling from the molten state decreases by grafting which is a good indication of crosslink formation, since crosslinking decreases the crystallizability of the polymer matrix.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pi.1995.210360108
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    Paper (German National Licenses)
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