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  • Phase separation  (1)
  • ideal gas  (1)
  • rate laws  (1)
  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Journal of statistical physics 38 (1985), S. 1027-1049 
    ISSN: 1572-9613
    Schlagwort(e): Kolmogorov system ; Markov chain ; rate laws ; correlation function decay ; relaxation process
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We investigate a piecewise linear (area-preserving) mapT describing two coupled baker transformations on two squares, with coupling parameter 0⩽c⩽1. The resulting dynamical system is Kolmogorov for anyc≠0. For rational values ofc, we construct a generating partition on whichT induces a Markov chain. This Markov structure is used to discuss the decay of correlation functions: exponential decay is found for a class of functions related to the partition. Explicit results are given forc=2−n. The macroscopic analog of our model is a leaking process between two (badly) stirred containers: according to the Markov analysis, the corresponding progress variable decays exponentially, but the rate coefficients characterizing this decay are not those determined from the one-way flux across the cell boundary. The validity of the macroscopic rate law is discussed.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of statistical physics 48 (1987), S. 1243-1248 
    ISSN: 1572-9613
    Schlagwort(e): Phase separation ; aggregation ; nonergodic processes
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract We study analytically the approach to equilibrium in a simple zero-temperature model for phase separation in a binary alloy, in which nearest neighbor interchange can occur only if the portion of AB bonds is thereby decreased. The approach to equilibrium is found analytically. Because of the existence of infinitely many possible stationary states, the asymptotic distribution of AB pairs depends on the details of the initial state and must be obtained by a recursion method.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Journal of statistical physics 33 (1983), S. 317-339 
    ISSN: 1572-9613
    Schlagwort(e): Chemical kinetics ; master equation ; ideal gas ; molecular dynamics ; irreversibility
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract Isomerization kinetics is studied on a one-dimensional ideal gas model with deterministic transitions. The concentrations of species are found to satisfy the phenomenological rate laws appropriate for diffusion-controlled kinetics, and the various correlations are determined. In the long-time regime, higher correlations present long tails reflecting a strongly non-Markovian evolution.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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