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Chlorine atom and ClO wall reaction products (1979)

Martin, L. Robbin ; Wren, Anthony G. ; Wun, Marilyn

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 11 (1979), S. 543-557

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Details

ISSN: 0538-8066

Schlagwort(e): Chemistry ; Physical Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The products of the heterogeneous reactions of chlorine atoms and chlorine oxide radicals with acid coated Pyrex walls have been directly determined for the first time. Contrary to the usual assumption that chlorine atoms recombine to form Cl2, we find that the major product is HCl, with small amounts of perchlorate also formed. Similarly, ClO radicals form HCl rather than Cl2. The source of hydrogen for these reactions is probably the water always found in this type of vacuum system. These results may change the interpretation of flow tube experiments with chlorine atoms. Application to the H + HCl reaction is discussed as an example.

Zusätzliches Material: 4 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/kin.550110507

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