ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Absolute rate constants at room temperature for the metathesis reaction have been measured under VLPP conditions: k1 = (2.0 ± 0.5) × 108M-1·s-1, k2 = (3.0 ± 0.7) × 108M-1·s-1. The radicals were generated through collisionless infrared-multiphoton decomposition of the corresponding iodides by irradiation from a high-power CO2-TEA laser. The reaction of Ċ2F5 and Ċ3F7 with \documentclass{article}\pagestyle{empty}\begin{document}$$\mathop {\rm N}\limits^{\rm .} {\rm O}_{\rm 2} $$\end{document} are briefly discussed in relation to the reaction of Ċ3 with \documentclass{article}\pagestyle{empty}\begin{document}$$\mathop {\rm N}\limits^{\rm .} {\rm O}_{\rm 2} $$\end{document}, which had been measured previously.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550140507
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