ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A kinetic study of the silver(I)-catalyzed oxidation of tris(1,10-phenanthroline)iron(II) with peroxodiphosphate was carried out by estimating tris-complex at 510 nm. The reaction is found to conform to the rate law (i). with K2 and K3 being the acid dissociation constants of H3P2O8- and H2P2O82-, respectively. The silver(I) catalysis in the reaction has been explained on the basis of complex formation between pdp and silver(I).
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550230603
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