ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Na2(Mo2vO4EDTA).4H2O crystals have been prepared in pure form. Kinetics for the oxidation of the compound by S2O82- have been studied spectrophotometrically in dilute sulphuric acid medium. The effects of hydrogen ion concentration, metal ion concentration, S2O82- ion concentration, and temperature on the process have been studied. Rate equations have been derived to explain the experimental observations. On the basis of the observations, suitable mechanisms have been suggested. The kinetic parameters E*, ΔH≠, and ΔS≠ of the process have also been determined. © 1997 John Wiley & Sons, Inc. Int J Chem Kinet 29: 269-274, 1997
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
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