ISSN:
0894-3230
Keywords:
Organic Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The recently developed σ-π energy separation technique was applied to substituted monocyclic ring systems. Modified correlation diagrams are presented which allow the influence of the substituent on the σ and π energies to be assessed. The slopes of the σ and π electron energy curves can be used to classify aromatic, non-aromatic and anti-aromatic compounds. A two-dimensional resonance coordinate representation shows a clustering of compounds of the three classes in distinctly different regions of this plane.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/poc.610061202
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