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Rate constant and activation energy for the gaseous reaction between hydroxyl and formaldehyde (1978)

Smith, Roland H.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 10 (1978), S. 519-527

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The rate constant k4 has been measured at 268°, 298°, and 334° K for the reaction CH2O + 2OH → CO + 2H2O relative to that for OH + OH (k2) by competition experiments in a discharge flow tube using mass-spectrometric analysis. Based on k2 = 2.24 × 10-12cm3/molec·sec at 298°K and E2 = 4 kJ/mol, k4 = (6.5 ± 1.5) × 10-12cm3/molec·sec at 298°K and E4 = (6 ± 2)kJ/mol.

Additional Material: 3 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550100509

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