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  • 1
    Electronic Resource
    Electronic Resource
    Ionic conductivity and side chain relaxation in polyglutamates having oligo(ethylene oxide) chains (1993)
    New York, NY : Wiley-Blackwell
    Polymers for Advanced Technologies 4 (1993), S. 179-187 
    Details
    ISSN: 1042-7147
    Keywords: Polymer electrolytes ; Poly(ethylene oxide) ; Polyglutamates ; α-Helix structure ; Ionic conductivity ; Dielectric relaxation ; Side chain relaxation ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: New polymer hosts to form polymer electrolytes, poly[methoxy-oligo(ethylene oxide)-L-glutamate] (PMnEOG, n = 1, 2, 3 and 7, n stands for the number of ethylene oxide units), have been prepared in order to study the correlation between the side chain relaxation and the ionic conductivity of PMnEOG/LiClO4 complexes. The main chains of PMnEOGs form a rigid rod-like structure (α-helix structure) in the solid state both in the absence and the presence of LiClO4. The oligo(ethylene oxide) side chains begin to be mobile at temperatures lower than 0°C, while the rigid main chains do not move up to 100°C. The side chains show a preferential solvation of incorporated LiClO4. The ionic conductivity of 10-7-10-6S/cm is attained in PM3EOG/LiClO4 and PM7EOG/LiClO4 complexes at room temperature, where only the short side chain motion contributes to the ionic transport. The temperature dependencies of the side chain relaxation time and ionic conductivity increase with increasing the side chain length when the temperature dependencies are normalized by the temperatures based on the glass transition temperatures of the side chains, which indicates strong cooperation between the side chain motion and the ion transport. The possibility of fast ion transport by short side chain relaxation is discussed.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pat.1993.220040218
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  • 2
    Electronic Resource
    Electronic Resource
    Charge transfer polycondensation of diethyl chelidonate with diamines in the presence of polyvinylcarbazole (1981)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 19 (1981), S. 1361-1366 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polycondensation of diethyl chelidonate (DEC), which contains an electron-accepting γ-pyrone nucleus, with hexamethylenediamine (HMD) takes place easily even at room temperature to form a corresponding polyamide. Since DEC was expected to form a charge transfer complex with an electron-donating compound such as polyvinylcarbazole (PVK), the polycondensation of DEC with diamines was carried out in the presence of PVK as a matrix. It was found that the rate of the polycondensation of DEC with diamines in dioxane was enhanced either by the presence of PVK or by the irradiation with ultraviolet (UV) light. Moreover, the polycondensation of DEC with HMD in the presence of PVK was accelerated by the UV irradiation, probably owing to the transfer of light energy.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1981.170190609
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  • 3
    Electronic Resource
    Electronic Resource
    Polycondensation of diethyl mucate with hexamethylenediamine in the presence of poly(vinyl pyridine) (1980)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 18 (1980), S. 933-938 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The polycondensation reaction of diethyl mucate (DEM) with hexamethylenediamine (HMD) was carried out in dimethyl sulfoxide (DMSO) at 60°C in the presence of poly(vinyl pyridine) (P-VPy) as a matrix polymer, which was expected to interact with DEM or the resulting polyamide which had pendant hydroxyl groups due to a hydrogen bonding. It was found that the polycondensation of DEM with HMD in the presence of poly(4-vinyl pyridine) (P-4VPy) produced a polyamide with a higher molecular weight than those in the presence of poly(2-vinyl pyridine) (P-2VPy) or in the absence of P-4VPy. The rate of the polycondensation, however, was rarely enhanced by polymer matrixes such as P-4VPy and P-2VPy. During polycondensation in the presence of P-4VPy a gelation of the reaction mixture was observed when the solution was kept at 30°C for several days. This might be ascribed to the formation of the polymer complex between resulting polyamide and P-4VPy during the polycondensation.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1980.170180314
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  • 4
    Electronic Resource
    Electronic Resource
    Polycondensation reaction of dimethyl tartrate with hexamethylenediamine in the presence of various matrices (1980)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 18 (1980), S. 939-948 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The polycondensation reaction of dimethyl tartrate (DMT) with hexamethylenediamine (HMD) was carried out in dimethyl sulfoxide (DMSO) at 60°C in the presence of various polymer matrices, which were expected to interact with DMT or the resulting polyamide which had pendant hydroxyl groups due to hydrogen bonding. It was found that the rate of polycondensation was enhanced by polymer matrices such as poly(vinyl pyrrolidone) (PVP), Pullulan (polysaccharide) (PF), and poly(vinyl alcohol) (PVA). The rate enhancement became more pronounced with increasing molecular weight of the polymer matrix. When polycondensation in the presence of PVA was carried out in DMSO, a polymer complex was produced. The formation of the polymer complex between the resulting polyamide and PVA during polycondensation was dependent on the concentration of monomers and also on PVA; a gelation of the solution was observed at a concentration of PVA.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1980.170180315
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  • 5
    Electronic Resource
    Electronic Resource
    Matrix polycondensation through hydrogen bonding interaction (1984)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 793-800 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Polycondensation of diesters having hydroxyl or pyridine groups was carried out with hexamethylenediamine (HMD) in the presence of (vinyl alcohol/vinyl acetate) copolymers as a matrix polymer. Apparent rates of the polycondensation of dimethyl tartrate (DMT) with HMD increased with increasing contents of PVA units in the copolymers and a strong entanglement between growing polyamide chains and PVA copolymers took place through the adsorption of HMD and DMT on the matrix copolymers. 2,6-Dimethyl pyridine dicarboxylate (2,6-DMP) reacted with HMD in the presence of the PVA copolymers or polysaccharide, while the rate enhancement effect of the matrix polymers was not significantly observed, as in the case of DMT. The effect of the matrix polymers on the polycondensation was discussed in terms of hydrogen bonding interactions.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1984.170220326
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  • 6
    Electronic Resource
    Electronic Resource
    Molecular-weight distribution of poly(P-phenylene terephthalamide) (1984)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 865-867 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1984.170220337
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  • 7
    Electronic Resource
    Electronic Resource
    Synthesis of aromatic polyesters by direct polycondensation with triphenylphosphine dichloride (1984)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 2705-2712 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Aromatic polyesters of high molecular weights were prepared by the direct polycondensation reaction of dicarboxylic acids and bisphenols or hydroxybenzoic acids with triphenylphosphine dichloride as a new condensing agent. Reaction conditions, including the amount of reagents and the concentration of monomer, solvent, and acid acceptor, were investigated. The aromatic polyester with the solution viscosity of 1.66 dL/g was obtained from bisphenol. A and terephthalic and isophthalic acid in quantitative yield under the optimum condition. The principal advantage of this condensing agent is that, based on the recycling system, recovered triphenylphosphine oxide can be reconverted to the reactive triphenylphosphine dichloride by treating with phosgene or oxalyl chloride.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1984.170221034
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  • 8
    Electronic Resource
    Electronic Resource
    Copolycondensation of hydroxyl diesters and active diesters with hexamethylenediamine (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 1523-1526 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1977.170150627
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  • 9
    Electronic Resource
    Electronic Resource
    Sequence distribution of repeating units of copolyamides by interfacial or solution methods (1978)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 16 (1978), S. 1991-2000 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The sequence distribution of repeating units of copolyamides from different diamines with isophthaloyl or terephthaloyl chlorides and dithiophenyl adipate have been investigated either by interfacial or solution methods to aim at the sequence control of the copolyamides by solvents.Copolycondensation of dithiophenyl adipate and isophthaloyl chloride with m-xylylenediamine in various solvents yielded copolyamides having different compositions of repeating units. Aprotic polar solvents produced random copolyamides having the same compositions as feed ratios of the comonomers, while nonpolar solvents yielded copolyamides rich in isophthaloyl units. Also the sequence distribution of the copolyamides from m- and p-phenylenediamines with isophthaloyl chloride was affected by solvents; nonpolar solvents produced copolyamides having a less-random and block character of the repeating units either by interfacial or solution methods.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1978.170160816
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  • 10
    Electronic Resource
    Electronic Resource
    Direct polycondensation of nylon salts by polyphosphates and imidazole (1979)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 17 (1979), S. 2401-2411 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Direct polycondensation of various nylon salts (salts of dicarboxylic acid and diamine) took place under mild conditions in the formation of polyamide in the presence of polyphosphates and organic bases. Among organic bases imidazole was the best in terms of polymer yields. The reactivity of the polyphosphates was arranged in following order: pyrophosphate ≅ tripolyphosphate 〉 tetrapolyphosphate. Otimum reaction conditions were investigated in terms of solvents, temperatures, and concentration of monomers. A reaction mechanism was proposed for the phosphorylation reaction, due to polyphosphates, which led to the direct polycondensation of nylon salts.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1979.170170812
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