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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Polymer International 36 (1995), S. 293-297 
    ISSN: 0959-8103
    Keywords: poly(2-hydroxyethyl methacrylate)(PHEMA) ; poly(styrene-co-acrylamide)(PSAm) ; blend miscibility ; hydrogel membrane ; protein controlled release ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The blend miscibility of poly(2-hydroxyethyl methacrylate) (PHEMA) and poly(styrene-co-acrylamide) (PSAm) was studied by DSC. A ‘miscible window’ was found in the range 47-57 mol% of acrylamide in blending PSAm with PHEMA (1:1 w/w) and was analysed by the mean-field theory. The water content and permeability coefficients of proteins were measured. The results show that the water content of the blends depends on the composition of PSAm and the blends, and the behaviour of blends swollen in water in Fickian type. However, the permeability of the solutes not only related to water content, but was also affected by phase behaviour. Controlled release of somatotropin from a cylindrical device coated with PHEMA/PSAm was achieved.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 20 (1982), S. 1271-1278 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Partially 2-carboxylbenzoyl (1) and 3-carboxyl-2-naphthoyl (2) substituted polystyrene were prepared by the Friedel-Crafts reaction of polystyrene with corresponding dicarboxylic anhydrides. Europium (III) salts of (1) and (2) and the copolymer of 4-vinylbenzoyl 2′-carboxylbenzoate-di(2-benzoyl benzoate) and styrene (5) were prepared. Polymer (5) was prepared by the copolymerization of the Eu3+ salt of 4-vinylbenzoyl 2′-benzoate and 2-benzoylbenzoate (ratio 1:2) with styrene. The fluorescence emission intensity was measured on fine powder samples. The intensity of (5) increased linearly as the Eu content increased. However, for the 1 and 2 systems the intensity reached a maximum at a Eu content as small as 0.5 wt% and remained constant when further increases were made. This phenomenon was accounted for by steric hindrance and a decrease in the freedom of bond rotation, which prevent the formation of multiple coordination linkages between Eu3+ and the benzoate groups.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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