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  • Physics  (1)
  • schlagzähes Polystyrol  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 260 (1982), S. 559-563 
    ISSN: 1435-1536
    Keywords: Bestrahlung ; Langzeitbestrahlung ; schlagzähes Polystyrol ; Strahlenabbau
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Abstract The radiation resistance of the high impact polystyrene Hostyren S 5300 of the Hoechst AG was investigated in two different experiments with gamma rays of a cobalt-60 source. Their radiation under exclosure of oxygen resulted in a steady increase of the ultimate tensile strength up to an energy dose of 3 MGy. During this experiment the elongation at break decreased (because of crosslinking of the polybutadiene phase) to half of its initial value at 1,9 MGy, the impact strength at 2,3 MGy, resp. A long time irradiation experiment of 10 years in air with low dose rate (3,72 mGy/s) resulted in considerable damage already at comparatively low doses: The ultimate tensile strength decreased to half of its initial value at about 0,9 MGy, the elongation at break at 0,4 MGy and the impact strength at 0,3 MGy resp. This behaviour is easily explained by radiation induced oxidation, especially of the rubber phase. — Storage of the sample for more than 14 years in the dark did not change their mechanical properties.
    Notes: Zusammenfassung In zwei Versuchen wurde die Strahlenbeständigkeit des schlagzähen Polystyrols Hostyren S 5300 der Hoechst AG untersucht. Bei der Bestrahlung unter Sauerstoffausschluß („Kurzzeitversuch“) ergab sich bis zur höchsten angewandten Dosis von 3 MJ/kg (3 MGy bzw. 300 Mrad) ein ständiger Anstieg der Reißfestigkeit. Die Reißdehnung wurde jedoch bereits bei 1,9 MJ/kg (1,9 MGy bzw. 190 Mrad), die Schlagzähigkeit bei 2,3 MJ/kg (2,3 MGy bzw. 230 Mrad) auf die Hälfte ihres Ausgangswertes verkleinert. Bei einer über 10 Jahre ausgedehnten praxisnahen Langzeitbestrahlung offen an der Luft versprödeten die Proben bereits bei erheblich kleineren Bestrahlungsdosen: Die Reißfestigkeit sank bei 0,9, die Reißdehnung bei 0,4 und die Schlagzähigkeit bei 0,3 MJ/kg auf die Hälfte ihres Ausgangswertes ab. Das Verhalten läßt sich durch Vernetzung (bei Sauerstoffausschluß) bzw. strahlenoxidativen Abbau (in Gegenwart von Sauerstoff) erklären. Bei einer Lagerung des schlagzähen Polystyrols über 14 Jahre im Dunkeln blieben Festigkeit und Dehnung praktisch unverändert.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 5 (1967), S. 183-192 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: High molecular copolymers of trioxane with different cyclic ethers and formals were produced by γ-radiation from a 60Co source. It was polymerized in the solid state at 53°C. Polymerization does not occur in the melt. Irradiation was carried out with exclusion of air at a dose rate of 7 × 103 rad/hr. The polymerization rate was increased very considerably in the presence of 1,3-dioxolane and epichlorhydrin; the addition of other comonomers may reduce the yield. The concentration of the comonomer is generally higher in the polymer than in the initial mix. These comonomers which increase the polymerization rate are introduced preferentially into the polymer chain; this is proved by the unstable polymer part and the thermal stability. Experiments with the trioxane-1,3-dioxolane system revealed that the unstable polymer part is markedly reduced and the heat stability considerably inproved with rising concentrations of this monomer. The thermal stability and the reduced viscosity of these copolymers are within the range of technical processability.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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