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A study of the cationic solid-state polymerization of 1,3,5-trithiane (1979)

Żuk, Aleksander ; Jȩczalik, Jerzy

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 17 (1979), S. 2233-2240

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ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The effect of various reaction parameters, such as temperature, catalyst, and concentration, on the cationic-initiated polymerization of 1,3,5-trithiane in solid state was studied and the apparent activation energies were estimated. A simple mathematical formula to describe the observed kinetic curves is proposed. The features observed are interpreted in terms of disordering a crystal structure during polymerization.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1979.170170730

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